全文获取类型
收费全文 | 8910篇 |
免费 | 1185篇 |
国内免费 | 976篇 |
专业分类
化学 | 2106篇 |
晶体学 | 89篇 |
力学 | 1236篇 |
综合类 | 209篇 |
数学 | 3705篇 |
物理学 | 3726篇 |
出版年
2024年 | 10篇 |
2023年 | 87篇 |
2022年 | 110篇 |
2021年 | 198篇 |
2020年 | 215篇 |
2019年 | 182篇 |
2018年 | 171篇 |
2017年 | 244篇 |
2016年 | 320篇 |
2015年 | 253篇 |
2014年 | 469篇 |
2013年 | 640篇 |
2012年 | 466篇 |
2011年 | 575篇 |
2010年 | 505篇 |
2009年 | 570篇 |
2008年 | 596篇 |
2007年 | 672篇 |
2006年 | 550篇 |
2005年 | 531篇 |
2004年 | 445篇 |
2003年 | 422篇 |
2002年 | 414篇 |
2001年 | 300篇 |
2000年 | 281篇 |
1999年 | 265篇 |
1998年 | 204篇 |
1997年 | 208篇 |
1996年 | 160篇 |
1995年 | 148篇 |
1994年 | 146篇 |
1993年 | 115篇 |
1992年 | 83篇 |
1991年 | 80篇 |
1990年 | 57篇 |
1989年 | 52篇 |
1988年 | 46篇 |
1987年 | 27篇 |
1986年 | 34篇 |
1985年 | 38篇 |
1984年 | 26篇 |
1983年 | 13篇 |
1982年 | 32篇 |
1981年 | 16篇 |
1980年 | 24篇 |
1979年 | 9篇 |
1978年 | 10篇 |
1977年 | 8篇 |
1976年 | 14篇 |
1972年 | 5篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Dr. Behdad Aghelnejad Prof. Geoffrey Bodenhausen Dr. Philippe Pelupessy 《Chemphyschem》2022,23(3):e202100786
Diffusion processes can be followed directly by recording one-dimensional images of a selected slice at variable intervals after selective inversion of the magnetization. The resulting diffusion coefficients of H2O and DMSO are consistent with earlier studies at different temperatures, obtained by monitoring the attenuation of NMR signals as a function of the gradient amplitude in gradient echo sequences. 相似文献
2.
3.
A complete manifold is said to be nonparabolic if it does admit a positive Green’s function. To ?nd a sharp geometric criterion for the parabolicity/nonparbolicity is an attractive question inside the function theory on Riemannian manifolds. This paper devotes to proving a criterion for nonparabolicity of a complete manifold weakened by the Ricci curvature. For this purpose, we shall apply the new Laplacian comparison theorem established by the ?rst author to show the existence of a non-constant bounded subharmonic function. 相似文献
4.
Two-stage ignition exists in the low-temperature combustion process of n-heptane and the first-stage ignition also shows a negative temperature coefficient(NTC) phenomenon. To study key reactions and understand chemical principles affecting the first-stage ignition of n-heptane, a lumped skeletal mechanism with 62 species is obtained based on the detailed NUIGMech1.0 mechanism using the directed relation graph method assisted by sensitivity analysis and isomer lumping. The lumped mechanism shows good performance on ignition delay time under wide conditions. The study revealed that the temperature after the first-stage ignition is higher and a larger amount of fuel is consumed at lower initial temperatures. The temperature at the first-stage ignition is relatively insensitive to the initial temperature. Further sensitivity analysis and reaction path analysis carried out based on the lumped mechanism show that the decomposition of RO2 to produce alkene and HO2is the most important reaction to inhibit the first-stage ignitions. The chain branching explosion closely related to the first-stage ignition will be terminated when the rate constant for the RO2 decomposition is larger than that of the isomerization of RO2 to produce QOOH. The NTC behavior as well as other characteristics of the first-stage ignition can be rationalized from the competition between these two reactions. 相似文献
5.
6.
A boundary‐fitted moving mesh scheme is presented for the simulation of two‐phase flow in two‐dimensional and axisymmetric geometries. The incompressible Navier‐Stokes equations are solved using the finite element method, and the mini element is used to satisfy the inf‐sup condition. The interface between the phases is represented explicitly by an interface adapted mesh, thus allowing a sharp transition of the fluid properties. Surface tension is modelled as a volume force and is discretized in a consistent manner, thus allowing to obtain exact equilibrium (up to rounding errors) with the pressure gradient. This is demonstrated for a spherical droplet moving in a constant flow field. The curvature of the interface, required for the surface tension term, is efficiently computed with simple but very accurate geometric formulas. An adaptive moving mesh technique, where smoothing mesh velocities and remeshing are used to preserve the mesh quality, is developed and presented. Mesh refinement strategies, allowing tailoring of the refinement of the computational mesh, are also discussed. Accuracy and robustness of the present method are demonstrated on several validation test cases. The method is developed with the prospect of being applied to microfluidic flows and the simulation of microchannel evaporators used for electronics cooling. Therefore, the simulation results for the flow of a bubble in a microchannel are presented and compared to experimental data. 相似文献
7.
A cost‐effective curvature calculation approach for interfacial flows on unstructured meshes 下载免费PDF全文
We present a simple and cost‐effective curvature calculation approach for simulations of interfacial flows on structured and unstructured grids. The interface is defined using volume fractions, and the interface curvature is obtained as a function of the gradients of volume fractions. The gradient computation is based on a recently proposed gradient recovery method that mimicks the least squares approach without the need to solve a system of equations and is quite easy to implement on arbitrary polygonal meshes. The resulting interface curvature is used in a continuum surface force formulation within the framework of a well‐balanced finite‐volume algorithm to simulate multiphase flows dominated by surface tension. We show that the proposed curvature calculation is at least as accurate as some of the existing approaches on unstructured meshes while being straightforward to implement on any mesh topology. Numerical investigations also show that spurious currents in stationary problems that are dependent on the curvature calculation methodology are also acceptably low using the proposed approach. Studies on capillary waves and rising bubbles in viscous flows lend credence to the ability of the proposed method as an inexpensive, robust, and reasonably accurate approach for curvature calculation and numerical simulation of multiphase flows. 相似文献
8.
9.
10.
Juan Colmenero 《Journal of Polymer Science.Polymer Physics》2019,57(18):1239-1245
The diffusion of polymer chains in miscible polymer blends with large dynamic asymmetry—those where the two blend components display very different segmental mobility—is not well understood yet. In the extreme case of the blend system of poly(ethylene oxide) (PEO) and poly(methyl methacrylate)(PMMA), the diffusion coefficient of PEO chains in the blend can change by more than five orders of magnitude while the segmental time scale hardly changes with respect to that of pure PEO. This behavior is not observed in blend systems with small or moderate dynamic asymmetry as, for instance, polyisoprene/poly(vinyl ethylene) blends. These two very different behaviors can be understood and quantitatively explained in a unified way in the framework of a memory function formalism, which takes into account the effect of the collective dynamics on the chain dynamics of a tagged chain. © 2019 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2019 , 57, 1239–1245 相似文献